Chemical and Physical Foundations

A 15.0 mL15.0\ \mathrm{mL} sample of 0.200 M Ba(OH)20.200\ \mathrm{M\ Ba(OH)_{2}} is diluted with water to a total volume of 300 mL300\ \mathrm{mL}. Assuming complete dissociation, what is the pH\mathrm{pH} of the resulting solution at 25∘C25^{\circ}\mathrm{C}?

Select one answer.

Answers

Show answer and explanationHide answer and explanation

Answer: C (12.3012.30)

Barium hydroxide dissociates completely according to Ba(OH)2(aq)\mathrm{Ba(OH)_{2}(aq) }→Ba2+(aq)\mathrm{{}\rightarrow Ba^{2+}(aq) }+2OH−(aq)\mathrm{{}+ 2OH^{-}(aq)}. The amount of hydroxide ions is 2(0.200 mol/L)2(0.200\ \mathrm{mol/L})(0.0150 L){}(0.0150\ \mathrm{L})=0.00600 mol{}=0.00600\ \mathrm{mol}. After dilution, [OH−][\mathrm{OH^{-}}]=0.00600 mol0.300 L{}=\frac{0.00600\ \mathrm{mol}}{0.300\ \mathrm{L}}=0.0200 M{}=0.0200\ \mathrm{M}. Thus, pOH\mathrm{pOH}=−log⁡(0.0200){}=-\log(0.0200)=1.70{}=1.70 and pH\mathrm{pH}=14.00−1.70{}=14.00-1.70=12.30{}=12.30.

Something unclear? Report this question with its page link.